Please use this identifier to cite or link to this item:
http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/10199| Title: | An intramolecular phosphine-oxide stabilized germanium(iv) di-cation with enhanced Lewis acidity and catalytic applications |
| Authors: | KUMARI, AKANKSHA PEDDI, BALAKRISHNA Yildiz, Cem. B. MAJUMDAR, MOUMITA Dept. of Chemistry |
| Keywords: | Chemistry 2025 |
| Issue Date: | May-2025 |
| Publisher: | Royal Society of Chemistry |
| Citation: | Chemical Communications, 61(35), 6506-6509. |
| Abstract: | This work reports the intramolecular phosphine-oxide stabilized tetra-coordinated germanium(IV) di-cation on an acenaphthene platform, 1iPrPO. Computational study shows that the positive charges and the acceptor orbitals are localized on the Ge site. 1iPrPO is Lewis super acidic, capable of catalysing hydrodefluorination reaction. 1iPrPO also catalyses hydrosilylation of electron-deficient aldehydes. |
| URI: | https://doi.org/10.1039/D5CC00250H http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/10199 |
| ISSN: | 1364-548X |
| Appears in Collections: | JOURNAL ARTICLES |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.