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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/10264| Title: | Access to Bis-Silylene-Stabilized Group 13 Cations |
| Authors: | GHOSH, MOUSHAKHI PANWARIA, PRAKASH Tothadi, Srinu KHAN, SHABANA Dept. of Chemistry |
| Keywords: | Anions Aromatic compounds Hydrocarbons Mathematical methods Molecular structure 2025 |
| Issue Date: | Jan-2025 |
| Publisher: | American Chemical Society |
| Citation: | Inorganic Chemistry, 64(02), 1110–1123. |
| Abstract: | Herein, we report the isolation of pyridine moiety-functionalized SiNSi pincer-based bis-silylene ligand (1) and its reactivity toward various halide precursors (X = Br and I) of group 13 elements (M = Al, Ga, and In). This gave us straightforward access to the SiNSi pincer-coordinated group 13 cations (2–7). These complexes are duly characterized by single-crystal X-ray diffraction studies, multinuclear magnetic resonance spectroscopy (1H, 13C, and 29Si), and high-resolution mass spectrometry techniques. Their electronic properties were further analyzed with the help of quantum chemical calculations. |
| URI: | https://doi.org/10.1021/acs.inorgchem.4c04703 http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/10264 |
| ISSN: | 0020-1669 1520-510X |
| Appears in Collections: | JOURNAL ARTICLES |
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