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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/10613| Title: | Silylene–copper(i) catalysis: regioselective protoboration of terminal alkynes |
| Authors: | KAULAGE, SANDEEP H. SHAH, BRIJ KUMAR PANDAY, RISHUKUMAR Sharma, Himanshu Vanka, Kumar KHAN, SHABANA Dept. of Chemistry |
| Keywords: | Alkynes; Catalysis; Copper; Hydrocarbons; Regioselectivity; Synthesis (chemical) 2025-DEC-WEEK1 TOC-DEC-2025 2025 |
| Issue Date: | Dec-2025 |
| Publisher: | Royal Society of Chemistry |
| Citation: | Chemical Communications, 61(19), 19652-19655., 61(19), 19652-19655. |
| Abstract: | Herein, we report an efficient regioselective protoboration of the terminal alkynes catalyzed by newly synthesized silylene–copper(i)–aryl complexes. This method offers a broad substrate scope, good functional-group compatibility, and a gram-scale synthetic ability. The insight into the mechanistic cycle is also provided with the support of experimental and theoretical studies. |
| URI: | https://doi.org/10.1039/D5CC06125C http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/10613 |
| ISSN: | 1364-548X |
| Appears in Collections: | JOURNAL ARTICLES |
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