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dc.contributor.authorZhao, Huien_US
dc.contributor.authorKlemmer, Lukasen_US
dc.contributor.authorCowley, Michael J.en_US
dc.contributor.authorMAJUMDAR, MOUMITAen_US
dc.contributor.authorHuch, Volkeren_US
dc.contributor.authorZimmer, Michaelen_US
dc.contributor.authorScheschkewitz, Daviden_US
dc.date.accessioned2018-08-06T04:03:53Z
dc.date.available2018-08-06T04:03:53Z
dc.date.issued2018-08en_US
dc.identifier.citationChemical Communications. Vol. 54(60).en_US
dc.identifier.issn1364-548Xen_US
dc.identifier.urihttp://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1132
dc.identifier.urihttps://doi.org/10.1039/c8cc03297aen_US
dc.description.abstract1,2,3-Trisilacyclopentadienes are obtained from the reactions of cyclotrisilene c-Si3R4 (R = iPr3C6H2) with phenyl and diphenyl acetylene, respectively. With 1,4-diethynyl benzene the crossconjugated bridging of two of the Si3C2 cycles by a paraphenylene linker is achieved. UV/ vis spectroscopy indicates a small but significant effect of cross-conjugation, which is confirmed by TD-DFT calculations. The formation mechanism of the 1,2,3trisilacyclopentadienes is elucidated by VT NMR.en_US
dc.language.isoenen_US
dc.publisherRoyal Society of Chemistryen_US
dc.subjectGroup 14 elementsen_US
dc.subjectMolecular-Orbital Methodsen_US
dc.subjectDouble-Bondsen_US
dc.subjectDisilenyl silyleneen_US
dc.subjectCrystal-Structureen_US
dc.subjectStable disilenesen_US
dc.subjectMultiple bondsen_US
dc.subjectSI=SI Bondsen_US
dc.subjectBasis-setsen_US
dc.subjectTOC-AUG-2018en_US
dc.subject2018en_US
dc.titlePhenylene-bridged cross-conjugated 1,2,3-trisilacyclopentadienesen_US
dc.typeArticleen_US
dc.contributor.departmentDept. of Chemistryen_US
dc.identifier.sourcetitleChemical Communicationsen_US
dc.publication.originofpublisherForeignen_US
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