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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1203| Title: | Reactivity of N-heterocyclic carbene, 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene, towards heavier halogens (Br-2 and I-2) |
| Authors: | PAL, SHIV Manae, Meghna A. Khade, Vikas V. KHAN, SHABANA Dept. of Chemistry |
| Keywords: | NHCs X-ray crystallography DFT NHCs adducts TOC-SEP-2018 2018 |
| Issue Date: | Jul-2018 |
| Publisher: | Indian Chemical Society |
| Citation: | Journal of the Indian Chemical Society. Vol. 95(7). |
| Abstract: | In the present study, the stoichiometry variation of N-heterocyclic carbene (NHC), 1 with halogens (Br-2 and I-2) shows its reactivity pattern toward halogens. The NHC, 1 was treated with 2.0, 1.0 and 0.5 equivalent of I-2 to afford the complex 2, 3 and 4 respectively. In the same fashion, the treatment of 1 with 2.0 and 1.0 equivalent of Br-2 resulted in the formation of complexes 5 and 6. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1203 - |
| ISSN: | 0019-4522 |
| Appears in Collections: | JOURNAL ARTICLES |
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