A Metal Coordination Polymer Framework Governed by Heat of Hydration for Non-invasive Differentiation of Alkali Metal Series

Please use this identifier to cite or link to this item: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1217

Title:	A Metal Coordination Polymer Framework Governed by Heat of Hydration for Non-invasive Differentiation of Alkali Metal Series
Authors:	Battu, Shateesh Itagi, Mahesh BHAT, ZAHID MANZOOR KHAIRE, SIDDHI KOTTAICHAMY, ALAGAR RAJA Sannegowda, Lokesh Koodlur THIMMAPPA, RAVIKUMAR THOTIYL, MUSTHAFA OTTAKAM Dept. of Chemistry
Keywords:	2018 Metal Coordination Polymer Framework Non-invasive Di fferentiation TOC-SEP-2018
Issue Date:	Oct-2018
Publisher:	American Chemical Society
Citation:	Analytical Chemistry
Abstract:	We illustrate that the extent of hydration and consequently the heat of hydration of alkali metal ions can be utilized to control their insertion/deinsertion chemistry in a redox active metal coordination polymer framework (CPF) electrode. The formal redox potential of CPF electrode for cation intercalation is inversely correlated to hydrated ionic radii, with clear distinction between the intercalation of ions across alkali metal series. This leads to non-invasive identification and differentiation of cations in the alkali metal series by utilizing a single sensing platform.
URI:	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1217 https://doi.org/10.1021/acs.analchem.8b03541
ISSN:	0003-2700
Appears in Collections:	JOURNAL ARTICLES

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