Please use this identifier to cite or link to this item:
http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1298| Title: | Bis(chlorogermyliumylidene) and its significant role in elusive reductive cyclization |
| Authors: | MAJUMDAR, MOUMITA RAUT, RAVINDRA K. SAHOO, PADMINI Kumar, Vikas Dept. of Chemistry |
| Keywords: | Chiral Piperazines Transition-Metals Radical Reactions Chemistry Coordination Germylene Dication State Germyliumylidene Diradicals TOC-OCT-2018 2018 |
| Issue Date: | Oct-2018 |
| Publisher: | Royal Society of Chemistry |
| Citation: | Chemical Communications. Vol. 54(77). |
| Abstract: | Bis(chlorogermyliumylidene) 2 has been strategically obtained within redox-active bis(-iminopyridine). Metal-free reduction of 2 followed by protonation led to elusive 2,3-di(pyridin-2-yl)piperazine with meso-stereoselectivity. Formation of persistent triplet diradicals upon reduction and isolation of piperazine stabilized Ge(ii) dication intermediates provide convincing evidence for the crucial role of [GeCl](+) units in reductive cyclization. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1298 https://doi.org/10.1039/c8cc06067c |
| ISSN: | 1364-548X |
| Appears in Collections: | JOURNAL ARTICLES |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.