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Please use this identifier to cite or link to this item: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1298
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dc.contributor.authorMAJUMDAR, MOUMITAen_US
dc.contributor.authorRAUT, RAVINDRA K.en_US
dc.contributor.authorSAHOO, PADMINIen_US
dc.contributor.authorKumar, Vikasen_US
dc.date.accessioned2018-10-12T05:13:33Z
dc.date.available2018-10-12T05:13:33Z
dc.date.issued2018-10en_US
dc.identifier.citationChemical Communications. Vol. 54(77).en_US
dc.identifier.issn1364-548Xen_US
dc.identifier.urihttp://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1298
dc.identifier.urihttps://doi.org/10.1039/c8cc06067cen_US
dc.description.abstractBis(chlorogermyliumylidene) 2 has been strategically obtained within redox-active bis(-iminopyridine). Metal-free reduction of 2 followed by protonation led to elusive 2,3-di(pyridin-2-yl)piperazine with meso-stereoselectivity. Formation of persistent triplet diradicals upon reduction and isolation of piperazine stabilized Ge(ii) dication intermediates provide convincing evidence for the crucial role of [GeCl](+) units in reductive cyclization.en_US
dc.language.isoenen_US
dc.publisherRoyal Society of Chemistryen_US
dc.subjectChiral Piperazinesen_US
dc.subjectTransition-Metalsen_US
dc.subjectRadical Reactionsen_US
dc.subjectChemistryen_US
dc.subjectCoordinationen_US
dc.subjectGermyleneen_US
dc.subjectDicationen_US
dc.subjectStateen_US
dc.subjectGermyliumylideneen_US
dc.subjectDiradicalsen_US
dc.subjectTOC-OCT-2018en_US
dc.subject2018en_US
dc.titleBis(chlorogermyliumylidene) and its significant role in elusive reductive cyclizationen_US
dc.typeArticleen_US
dc.contributor.departmentDept. of Chemistryen_US
dc.identifier.sourcetitleChemical Communicationsen_US
dc.publication.originofpublisherForeignen_US
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