Please use this identifier to cite or link to this item: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1310
Title: Additive Free Fe-Catalyzed Conversion of Nitro to Aldehyde under Continuous Flow Module
Authors: AGALAVE, SANDIP G.
CHAUDHARI, MORESHWAR B.
BISHT, GIRISH SINGH
GNANAPRAKASAM, BOOPATHY
Dept. of Chemistry
Keywords: Continuous flow reactions
Fe-catalyzed reaction
Heterogeneous catalyst
Nef reaction
TOC-OCT-2018
2018
Issue Date: Aug-2018
Publisher: American Chemical Society
Citation: ACS Sustainable Chemistry & Engineering Vol. 6(10)
Abstract: Fe-catalyzed direct transformation of nitro compounds to aldehyde under batch/continuous flow module is reported. This catalytic transformation is highly selective for syntheses of various aldehydes and does not require any additional additives such as bases and oxidants. Furthermore, the heterogeneous Fe-zeolite catalyst is recoverable and reusable for more than five cycles and offers gram-scale synthesis without the loss of catalytic efficiency. This heterogeneous catalyst has a maximum TOF of 5.93 h(-1).
URI: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1310
https://doi.org/10.1021/acssuschemeng.8b02090
ISSN: 2168-0485
Appears in Collections:JOURNAL ARTICLES

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