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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1328| Title: | Anion Selective Ion Channel Constructed from a Self-Assembly of Bis(cholate)-Substituted Fumaramide |
| Authors: | Malla, Javid Ahmad Roy, Arundhati TALUKDAR, PINAKI Dept. of Chemistry |
| Keywords: | Apoptosis-Inducing Activity Chloride Transport Angstrom Resolution Cholic-Acid Membrane Cells Catalysis Peptide Barrels TOC-OCT-2018 2018 |
| Issue Date: | Oct-2018 |
| Publisher: | American Chemical Society |
| Citation: | Organic Letters Vol. 20(19) |
| Abstract: | The self-assembled ion channel constructed from bis(cholate)-substituted fumaramide is reported. Such ion channel formation was favored by intermolecular hydrogen bonding interactions among fumaramide moieties. Fluorescence kinetics experiments and planar bilayer conductance measurements confirmed the selective chloride transport through the channel. Theoretical calculations were done to confirm the hydrogen bonded self-assembly of fumaramides and chloride recognition within the cavity. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1328 https://doi.org/10.1021/acs.orglett.8b02115 |
| ISSN: | 1523-7060 |
| Appears in Collections: | JOURNAL ARTICLES |
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