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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1554| Title: | A Vinyl-Boronate Ester-Based Persulfide Donor Controllable by Hydrogen Peroxide, a Reactive Oxygen Species (ROS) |
| Authors: | BORA, PRERONA Chauhan, Preeti MANNA, SUMAN CHAKRAPANI, HARINATH Dept. of Chemistry |
| Keywords: | Small-Molecule Mycobacterium-Tuberculosis Equilibrium-Constants Sulfide Protects Chemical Biology Keto-Enol Disulfides Generation Activation Precursors TOC-JAN-2019 2018 |
| Issue Date: | Dec-2018 |
| Publisher: | American Chemical Society |
| Citation: | Organic Letters, Vol. 20(24) pp7916-7920. |
| Abstract: | A vinyl boronate ester-based persulfidating agent that is selectively activated by hydrogen peroxide, which is a reactive oxygen species (ROS), and efficiently generated a persulfide by a hitherto unexplored 1,4-O,S-relay mechanism is reported. This donor was found to protect cells from cytotoxicity induced by oxidants, and the major byproduct is cinnamaldehyde, which is widely used in the food industry as an additive. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1554 https://doi.org/10.1021/acs.orglett.8b03471 |
| ISSN: | 1523-7060 1523-7052 |
| Appears in Collections: | JOURNAL ARTICLES |
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