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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1593| Title: | Folding dynamics of flavin adenine dinucleotide (FAD) inside non-aqueous and aqueous reverse micelles |
| Authors: | Sengupta, Abhigyan Gavvala, Krishna Raj Kumar Koninti Chaudhuri, Haribandhu HAZRA, PARTHA Dept. of Chemistry |
| Keywords: | Dynamics of FAD MeOH flavin adenine dinucleotide Non-aqueous Aqueous reverse micelles 2013 |
| Issue Date: | Oct-2013 |
| Publisher: | Elsevier B.V. |
| Citation: | Chemical Physics Letters, 584, 67-73. |
| Abstract: | Present Letter describes dynamics of FAD in non-aqueous and aqueous reverse micelles (RMs). FAD in non-aqueous reverse micelles (containing MeOH, glycerol, formamide or DMF) shows a prominent rise of quantum yield with increasing solvent loading, whereas in water RM FAD shows a rise in quantum yield only up to w0 = 10 and afterwards drops sharply up to bulk. A relative difference in polarity of dry AOT to solvent loaded RMs can be attributed to the opposite trend of changes in emission. This Letter of FAD in different RMs and its preferential orientation might be useful for understanding FAD dynamics inside flavoproteins. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1593 https://doi.org/10.1016/j.cplett.2013.08.028 |
| ISSN: | 0009-2614 |
| Appears in Collections: | JOURNAL ARTICLES |
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