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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1620| Title: | Metal‐Assisted Cyclomerization of N‐Confused Dipyrrins into Expanded Norroles |
| Authors: | GADEKAR, SANTOSH C. REDDY, BADDIGAM KIRAN ANAND, V. G. Dept. of Chemistry |
| Keywords: | Metal‐Assisted Cyclomerization N‐Confused Dipyrrins Expanded Norroles 2013 |
| Issue Date: | Jul-2013 |
| Publisher: | Wiley |
| Citation: | Angewandte Chemie International Edition, 52(28), |
| Abstract: | Neoconfusion: In contrast to metal ligation by dipyrrin (see scheme, left), N‐confused dipyrrin undergoes cyclomerization with various metal salts to form NCNCNC and NCNCNCNC expanded norroles (see scheme, right), novel isomers of 24 π rosarin and 32 π octaphyrin with C–N linked bipyrrole units with near‐planar conformations in the solid state. They also exhibit paratropic ring‐current effects typical of antiaromatic porphyrinoids. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1620 https://doi.org/10.1002/anie.201303184 |
| ISSN: | 1433-7851 1521-3773 |
| Appears in Collections: | JOURNAL ARTICLES |
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