Please use this identifier to cite or link to this item: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1622
Title: Ammonia Coordination Introducing a Magnetic Moment in an On‐Surface Low‐Spin Porphyrin
Authors: Wackerlin, Christian
Tarafder, Kartick
Girovsky, Jan
Nowakowski, Jan
Hahlen, Tatjana
Shchyrba, Aneliia
Siewert, Dorota
Kleibert, Armin
Nolting, Frithjof
Oppeneer, Peter M.
Jung, Thomas A.
BALLAV, NIRMALYA
Dept. of Chemistry
Keywords: Ammonia Coordination
Ammonia Coordination
Low-Spin Porphyrin
Capability of NH3
Molecular spintronics
2013
Issue Date: Apr-2013
Publisher: Wiley
Citation: Angewandte Chemie International Edition, 52(17), 4568-4571.
Abstract: The molecular spin state of NiII porphyrin, supported on a ferromagnetic Co surface, can be reversibly switched between spin‐off (S=0) and spin‐on (S=1) states upon coordination and decoordination of the gaseous ligand NH3, respectively (see picture). This finding clearly indicates the possible use of the system as a single‐molecule‐based magnetochemical sensor and in spintronics.
URI: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1622
https://doi.org/10.1002/anie.201208028
ISSN: 1433-7851
1521-3773
Appears in Collections:JOURNAL ARTICLES

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