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Title: | Ammonia Coordination Introducing a Magnetic Moment in an On‐Surface Low‐Spin Porphyrin |
Authors: | Wackerlin, Christian Tarafder, Kartick Girovsky, Jan Nowakowski, Jan Hahlen, Tatjana Shchyrba, Aneliia Siewert, Dorota Kleibert, Armin Nolting, Frithjof Oppeneer, Peter M. Jung, Thomas A. BALLAV, NIRMALYA Dept. of Chemistry |
Keywords: | Ammonia Coordination Ammonia Coordination Low-Spin Porphyrin Capability of NH3 Molecular spintronics 2013 |
Issue Date: | Apr-2013 |
Publisher: | Wiley |
Citation: | Angewandte Chemie International Edition, 52(17), 4568-4571. |
Abstract: | The molecular spin state of NiII porphyrin, supported on a ferromagnetic Co surface, can be reversibly switched between spin‐off (S=0) and spin‐on (S=1) states upon coordination and decoordination of the gaseous ligand NH3, respectively (see picture). This finding clearly indicates the possible use of the system as a single‐molecule‐based magnetochemical sensor and in spintronics. |
URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1622 https://doi.org/10.1002/anie.201208028 |
ISSN: | 1433-7851 1521-3773 |
Appears in Collections: | JOURNAL ARTICLES |
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