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Please use this identifier to cite or link to this item: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1623
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dc.contributor.authorNowakowski, Janen_US
dc.contributor.authorWackerlin, Christianen_US
dc.contributor.authorGirovsky, Janen_US
dc.contributor.authorSiewert, Dorotaen_US
dc.contributor.authorJung, Thomas A.en_US
dc.contributor.authorBALLAV, NIRMALYAen_US
dc.date.accessioned2019-02-14T05:01:22Z
dc.date.available2019-02-14T05:01:22Z
dc.date.issued2013-02en_US
dc.identifier.citationChemical Communications, 49(23), 2347-2349.en_US
dc.identifier.issn1359-7345en_US
dc.identifier.issn1364-548Xen_US
dc.identifier.urihttp://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1623-
dc.identifier.urihttps://doi.org/10.1039/C3CC39134Een_US
dc.description.abstracthe presence of an oxygen reconstruction on the Cu(001) surface results in the self-metalation of 5,10,15,20-tetraphenylporphyrin (2HTPP) below room temperature (at -285 K), in contrast to 2 HTPP on the bare Cu(001) substrate, where a temperature of -450 K is required. This study demonstrates the decisive impact of a surface reconstruction on the redox reaction in the solvent-free ultra-high vacuum environment.en_US
dc.language.isoenen_US
dc.publisherRoyal Society of Chemistryen_US
dc.subjectPorphyrin metalationen_US
dc.subjectRedox reactionen_US
dc.subjectSurface reconstructionen_US
dc.subjectOxygen reconstructionen_US
dc.subject2013en_US
dc.titlePorphyrin metalation providing an example of a redox reaction facilitated by a surface reconstructionen_US
dc.typeArticleen_US
dc.contributor.departmentDept. of Chemistryen_US
dc.identifier.sourcetitleChemical Communicationsen_US
dc.publication.originofpublisherForeignen_US
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