Please use this identifier to cite or link to this item:
http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1623| Title: | Porphyrin metalation providing an example of a redox reaction facilitated by a surface reconstruction |
| Authors: | Nowakowski, Jan Wackerlin, Christian Girovsky, Jan Siewert, Dorota Jung, Thomas A. BALLAV, NIRMALYA Dept. of Chemistry |
| Keywords: | Porphyrin metalation Redox reaction Surface reconstruction Oxygen reconstruction 2013 |
| Issue Date: | Feb-2013 |
| Publisher: | Royal Society of Chemistry |
| Citation: | Chemical Communications, 49(23), 2347-2349. |
| Abstract: | he presence of an oxygen reconstruction on the Cu(001) surface results in the self-metalation of 5,10,15,20-tetraphenylporphyrin (2HTPP) below room temperature (at -285 K), in contrast to 2 HTPP on the bare Cu(001) substrate, where a temperature of -450 K is required. This study demonstrates the decisive impact of a surface reconstruction on the redox reaction in the solvent-free ultra-high vacuum environment. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1623 https://doi.org/10.1039/C3CC39134E |
| ISSN: | 1359-7345 1364-548X |
| Appears in Collections: | JOURNAL ARTICLES |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.