Please use this identifier to cite or link to this item:
http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1629| Title: | Zn(ii) coordination polymer of an in situ generated 4-pyridyl (4Py) attached bis(amido)phosphate ligand, [PO2(NH4Py)2]− showing preferential water uptake over aliphatic alcohols |
| Authors: | GUPTA, ARVIND K. Nagarkar, Sanjog S. BOOMISHANKAR, RAMAMOORTHY Dept. of Chemistry |
| Keywords: | Coordination polymer Aliphatic alcohols Polymorphic 2D-coordination Preferential adsorption of water vapour 2013 |
| Issue Date: | May-2013 |
| Publisher: | Royal Society of Chemistry |
| Citation: | Dalton Transactions, 42(30), 10964-10970. |
| Abstract: | Two polymorphic 2D-coordination polymers of composition [ZnL(HCO2)]∞ were synthesized from an in situ generated ligand [PO2(NH4Py)2]− (L−). The ligand L− was generated by a facile metal-assisted P–N bond hydrolysis reaction from the corresponding phosphonium salt 1, [P(NH4Py)4]Cl, or from the neutral phosphoric triamide 2, [PO(NH4Py)3]. The de-solvated sample of the polymer [ZnL(HCO2)]∞ features polar micropores and shows a type I isotherm for CO2 sorption whereas a type II behaviour was observed for N2. The vapour sorption isotherm of the de-solvated sample of [ZnL(HCO2)]∞ shows preferential adsorption of water vapour over aliphatic alcohols. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1629 https://doi.org/10.1039/C3DT51123E |
| ISSN: | 1477-9226 1477-9234 |
| Appears in Collections: | JOURNAL ARTICLES |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.