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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1637| Title: | A Continuous π-Stacked Starfish Array of Two-Dimensional Luminescent MOF for Detection of Nitro Explosives |
| Authors: | Chaudhari, Abhijeet K. Nagarkar, Sanjog S. JOARDER, BIPLAB GHOSH, SUJIT K. Dept. of Chemistry |
| Keywords: | π-Stacked Starfish Two-Dimensional Luminescent Detection of Nitro Explosives Fluorescence quenching mechanism 2013 |
| Issue Date: | Aug-2013 |
| Publisher: | American Chemical Society |
| Citation: | Crystal Growth and Design, 13(8), 3716-3721. |
| Abstract: | A highly luminescent two-dimensional metal–organic framework (MOF) containing continuous π-stack cylindrical arrays in a backbone has been designed and synthesized. Here, we demonstrate the “supramolecular wire effect” on a MOF surface for fast and reversible solid-state detection of both aliphatic and aromatic nitro explosives via a fluorescence quenching mechanism. A possible quenching mechanism by a supramolecular wire effect has been demonstrated by structural analysis of host–guest π-stacked interactions and guest sorption studies. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1637 https://doi.org/10.1021/cg400749m |
| ISSN: | 1528-7483 1528-7505 |
| Appears in Collections: | JOURNAL ARTICLES |
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