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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1639| Title: | An asymmetrically connected hexanuclear DyIII6 cluster exhibiting slow magnetic relaxation |
| Authors: | Mukherjee, Soumya Chaudhari, Abhijeet K. Xue, Shufang Tang, Jinkui GHOSH, SUJIT K. Dept. of Chemistry |
| Keywords: | Dysprosium Cluster compounds Asymmetry Slow magnetic relaxation Two high-anisotropy Asymmetric homometallic 2013 |
| Issue Date: | Sep-2013 |
| Publisher: | Elsevier B.V. |
| Citation: | Inorganic Chemistry Communications, Vol.35, 144-148. |
| Abstract: | A new hexanuclear dysprosium(III) cluster [Dy6(L)7(HL)(MeOH)2(H2O)(OH)2(OAc)] (1) has been synthesized from the schiff base ligand o-phenolsalicylimine and dysprosium nitrate. This unique DyIII6 cluster, constituted of an exclusive combination of two vertex-sharing and one edge-sharing high-anisotropy Dy3 triangles assembled together forming an unprecedentedly asymmetric homometallic DyIII6 core, shows slow relaxation of the magnetization. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1639 https://doi.org/10.1016/j.inoche.2013.06.027 |
| ISSN: | 1387-7003 |
| Appears in Collections: | JOURNAL ARTICLES |
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