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Title: | Ruthenium-catalyzed intramolecular selective halogenation of O-methylbenzohydroximoyl halides: a new route to halogenated aromatic nitriles |
Authors: | Chinnagolla, Ravi Kiran Pimparkar, Sandeep JEGANMOHAN, MASILAMANI Dept. of Chemistry |
Keywords: | Ruthenium-catalyzed Oxidative cyclization Aromatic and heteroaromatic Route to isoquinolones Halogenated aromatic nitriles Intramolecular halogenation N-methoxybenzimidoyl 2013 |
Issue Date: | Feb-2013 |
Publisher: | Royal Society of Chemistry |
Citation: | Chemical Communications, 49(54), 3146-3148. |
Abstract: | The intramolecular halogenation of O-methylbenzohydroximoyl halides in the presence of a Ru catalyst and the ligand diphenylacetylene afforded halo substituted aromatic nitriles in a highly regioselective manner. Further, substituted nitriles were converted into substituted tetrazole derivatives in the presence of NaN3 and I2. |
URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1647 https://doi.org/10.1039/C3CC41124A |
ISSN: | 1359-7345 1364-548X |
Appears in Collections: | JOURNAL ARTICLES |
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