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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1948| Title: | A cationic copper(i) iodide cluster MOF exhibiting unusual ligand assisted thermochromism |
| Authors: | Yadav, Ashok Srivastava, Anant Kumar Balamurugana, Ayyakkalai BOOMISHANKAR, RAMAMOORTHY Dept. of Chemistry |
| Keywords: | Cationic copper(I) iodide cluster MOF exhibiting unusual Assisted thermochromism Coordination compounds 2014 |
| Issue Date: | Apr-2014 |
| Publisher: | Royal Society of Chemistry |
| Citation: | Dalton Transactions, 43(22), 8166-8169. |
| Abstract: | BBy employing a tridentate thiophosphoramide ligand, [(NHAQ)3P[double bond, length as m-dash]S] (AQ = 3-quinolinyl), a cationic MOF, 1 {[Cu6I5(L1)2](OH)·3DMF·2.5MeOH}n, was synthesized. Photo-physical studies on the 2D-MOF 1 showed an unusual thermochromic behaviour emitting a blue fluorescence at 298 K due to the AQ chromophore and an orange-yellow phosphorescence at 77 K due to the [Cu6I5]+ unit. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1948 https://doi.org/10.1039/C4DT00050A |
| ISSN: | 1477-9226 1477-9234 |
| Appears in Collections: | JOURNAL ARTICLES |
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