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Title: | Ruthenium-Catalyzed Dimerization of Propiolates: A Simple Route to α-Pyrones |
Authors: | Manikandan, Rajendran JEGANMOHAN, MASILAMANI Dept. of Chemistry |
Keywords: | Ruthenium-Catalyzed Dimerization Propiolates Simple Route Pyrones Intermolecular dimerization 2014 |
Issue Date: | Feb-2014 |
Publisher: | American Chemical Society |
Citation: | Organic Letters, 16(3), 652-655. |
Abstract: | A ruthenium-catalyzed regioselective intermolecular multistep homo- and heterodimerization of substituted propiolates providing α-pyrone-5-carboxylates and α-pyrone-6-carboxylates is described. The synthetic utilities of α-pyrone derivatives are shown. The proposed mechanism is strongly supported by experimental evidence. |
URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1959 https://doi.org/10.1021/ol4035929 |
ISSN: | 1523-7060 1523-7052 |
Appears in Collections: | JOURNAL ARTICLES |
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