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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1960| Title: | Ruthenium-Catalyzed Hydroarylation of Anilides with Alkynes: An Efficient Route to Ortho-Alkenylated Anilines |
| Authors: | Manikandan, Rajendran JEGANMOHAN, MASILAMANI Dept. of Chemistry |
| Keywords: | Ruthenium-Catalyzed Hydroarylation Anilides with Alkynes Ortho-Alkenylated Anilines Presence of HCl 2014 |
| Issue Date: | Feb-2014 |
| Publisher: | American Chemical Society |
| Citation: | Organic Letters, 16(3),912-915. |
| Abstract: | Acetanilides reacted with symmetrical as well as unsymmetrical alkynes in the presence of [{RuCl2(p-cymene)}2], pivalic acid, and AgSbF6 in iso-PrOH providing ortho-alkenylated acetanilides in a highly regio- and stereoselective manner. Later, ortho-alkenylated acetanilides were converted into ortho-alkenylated anilines in the presence of HCl. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1960 https://doi.org/10.1021/ol403666s |
| ISSN: | 1523-7060 1523-7052 |
| Appears in Collections: | JOURNAL ARTICLES |
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