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Title: | Ruthenium-Catalyzed Cyclization of Anilides with Substituted Propiolates or Acrylates: An Efficient Route to 2-Quinolinones |
Authors: | Manikandan, Rajendran JEGANMOHAN, MASILAMANI Dept. of Chemistry |
Keywords: | Ruthenium-Catalyzed Cyclization Substituted Propiolates Efficient Route to 2-Quinolinones Efficient Route to 2-Quinolinones 2014 |
Issue Date: | Jul-2014 |
Publisher: | American Chemical Society |
Citation: | Organic Letters, 16(13),3568-3571. |
Abstract: | A Ru-catalyzed cyclization of anilides with propiolates or acrylates affording 2-quinolinones having diverse functional groups in good to excellent yields is described. Later, 2-quinolinones were converted into 3-halo-2-quinolinones and 2-chloroquinolines. The proposed mechanism was strongly supported by experimental evidence and deuterium labeling studies. |
URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1963 https://doi.org/10.1021/ol501548e |
ISSN: | 1523-7060 1523-7052 |
Appears in Collections: | JOURNAL ARTICLES |
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