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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1965| Title: | Ruthenium-Catalyzed Cyclization of Aromatic Nitriles with Alkenes: Stereoselective Synthesis of (Z)-3-Methyleneisoindolin-1-ones |
| Authors: | REDDY, MALLU CHENNA JEGANMOHAN, MASILAMANI Dept. of Chemistry |
| Keywords: | Ruthenium-catalyzed Aromatic boronic acids Phenanthridines and carbazoles Aromatic boronic Coordinating oxygen Aromatic Nitriles Ruthenium catalyst Aromatic amides 2014 |
| Issue Date: | Sep-2014 |
| Publisher: | American Chemical Society |
| Citation: | Organic Letters, 16(18), 4866-4869. |
| Abstract: | Aromatic nitriles underwent cyclization with activated alkenes in the presence of a ruthenium catalyst, AgSbF6, and Cu(OAc)2·H2O providing substituted 3-methyleneisoindolin-1-ones with high Z-stereoselectivity. The Z-stereoselectivity of the 3-methyleneisoindolin-1-one moiety was controlled by the intramolecular hydrogen bonding. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1965 https://doi.org/10.1021/ol502375p |
| ISSN: | 1523-7060 1523-7052 |
| Appears in Collections: | JOURNAL ARTICLES |
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