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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1970| Title: | Structures and Magnetic Properties of Two Analogous Dy6 Wheels with Electron-Donation and -Withdrawal Effects |
| Authors: | JOARDER, BIPLAB Mukherjee, Soumya Xue, Shufang Tang, Jinkui GHOSH, SUJIT K. Dept. of Chemistry |
| Keywords: | Structures and Magnetic Two Analogous Dy6 Wheels Withdrawal Effects Incongruent magnetic 2014 |
| Issue Date: | Jul-2014 |
| Publisher: | American Chemical Society |
| Citation: | Inorganic Chemistry, 53(14), 7554-7560. |
| Abstract: | Two new hexanuclear symmetric dysprosium wheels, namely, [Dy6(L1)6(L′)6(OCH3)6(2CH3OH)] and [Dy6(L2)6(L′)6(OCH3)6(2CH3OH)] (L1H = pivalic acid and L2H = 3,5-dinitrobenzoic acid, L′H= 2,6-dimethoxyphenol) were isolated employing a mixed-ligand strategy. The strategic introduction of two different auxiliary groups with diverse steric effects and electrostatic actions affect the magnetic coupling and local anisotropy of DyIII ion, therefore exhibiting dissimilar magnetic behaviors. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1970 https://doi.org/10.1021/ic500875m |
| ISSN: | 0020-1669 1520-510X |
| Appears in Collections: | JOURNAL ARTICLES |
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