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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2103| Title: | A 1,3-amino group migration route to form acrylamidines |
| Authors: | Chauhan, Dinesh Pratapsinh Varma, Sreejith Jayasree Vijeta, Arjun BANERJEE, PALLAVI TALUKDAR, PINAKI Dept. of Chemistry |
| Keywords: | A 1,3-amino group migration Acrylamidines Bioconjugation Instantaneously participates 2013 |
| Issue Date: | Oct-2013 |
| Publisher: | Royal Society of Chemistry |
| Citation: | Chemical Communications, 50(3), 323-325. |
| Abstract: | A novel 1,3-amino group migration strategy for the synthesis of acrylamidines is presented. Cu(I) catalyzed reaction of N,N-disubstituted propargylamine with tosylazide generates a highly reactive ketenimine intermediate which is trapped by a tethered amino group leading to the rearrangement reaction. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2103 https://doi.org/10.1039/C3CC47182A |
| ISSN: | 1359-7345 1364-548X |
| Appears in Collections: | JOURNAL ARTICLES |
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