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Title: | Selective and Sensitive Aqueous‐Phase Detection of 2,4,6‐Trinitrophenol (TNP) by an Amine‐Functionalized Metal–Organic Framework |
Authors: | JOARDER, BIPLAB DESAI, AAMOD V. SAMANTA, PARTHA Mukherjee, Soumya GHOSH, SUJIT K. Dept. of Chemistry |
Keywords: | Sensitive Aqueous-Phase Detection Amine-Functionalized Metal Organic Framework Coordination polymers 2015 |
Issue Date: | Jan-2015 |
Publisher: | Wiley |
Citation: | Chemistry - A European Journal, 21(3), 965-969. |
Abstract: | Highly selective and sensitive aqueous‐phase detection of nitro explosive 2,4,6‐trinitrophenol (TNP) by a hydrolytically stable 3D luminescent metal–organic framework is reported. The compound senses TNP exclusively even in the presence of other nitro‐compounds, with an unprecedented sensitivity in the MOF regime by means of strategic deployment of its free amine groups. Such an accurate sensing of TNP, widely recognized as a harmful environmental contaminant in water media, establishes this new strategic approach as one of the frontiers to tackle present‐day security and health concerns in a real‐time scenario. |
URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2188 https://doi.org/10.1002/chem.201405167 |
ISSN: | 0947-6539 1521-3765 |
Appears in Collections: | JOURNAL ARTICLES |
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