Selective Anion Exchange and Tunable Luminescent Behaviors of Metal–Organic Framework Based Supramolecular Isomers

Please use this identifier to cite or link to this item: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2192

Title:	Selective Anion Exchange and Tunable Luminescent Behaviors of Metal–Organic Framework Based Supramolecular Isomers
Authors:	Manna, Biplab Singh, Shweta Karmakar, Avishek DESAI, AAMOD V. GHOSH, SUJIT K. Dept. of Chemistry
Keywords:	Anion Exchange Luminescent Behaviors Supramolecular Isomers Organic Framework SEM images 2015
Issue Date:	Jan-2015
Publisher:	American Chemical Society
Citation:	Inorganic Chemistry, 54 (1), 110-116.
Abstract:	Owing to the conformational (cis or trans) flexibility of a N-donor ligand, the combinations of the same and Cd(ClO4)2 under variable solvent templates afforded two supramolecular isomers based on two-dimensional metal–organic frameworks. Both compounds contain weakly coordinating ClO4– anions attached to the metal centers. Both frameworks showed facile anion exchange behaviors with various kinds of foreign anions. Moreover, both frameworks showed anion-driven structural dynamism and exhibited the preferential uptake of strongly coordinating anions over others. Anion-regulated modulation in luminescent behaviors was also observed in both cases.
URI:	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2192 https://doi.org/10.1021/ic501879w
ISSN:	0020-1669 1520-510X
Appears in Collections:	JOURNAL ARTICLES

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