An Amide‐Functionalized Dynamic Metal–Organic Framework Exhibiting Visual Colorimetric Anion Exchange and Selective Uptake of Benzene over Cyclohexane

Please use this identifier to cite or link to this item: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2193

Title:	An Amide‐Functionalized Dynamic Metal–Organic Framework Exhibiting Visual Colorimetric Anion Exchange and Selective Uptake of Benzene over Cyclohexane
Authors:	Karmakar, Avishek DESAI, AAMOD V. Manna, Biplab JOARDER, BIPLAB GHOSH, SUJIT K. Dept. of Chemistry
Keywords:	Amide-Functionalized Metal-Organic Framework Visual Colorimetric Benzene over Cyclohexane 2015
Issue Date:	May-2015
Publisher:	Wiley
Citation:	Chemistry - A European Journal, 21(19), 7071-7076.
Abstract:	A novel porous metal–organic framework (MOF) architecture is formed by a neutral amide‐functionalized ligand and copper(II). Upon desolvation, this compound undergoes a dynamic structural transformation from a one‐dimensional (1D) porous phase to a two‐dimensional (2D) non‐porous phase that shows selective uptake of benzene over cyclohexane. The as‐synthesized compound also acts as a visual colorimetric anion sensor for thiocyanate.
URI:	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2193 https://doi.org/10.1002/chem.201406233
ISSN:	0947-6539 1521-3765
Appears in Collections:	JOURNAL ARTICLES

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