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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2196| Title: | Single-crystal-to-single-crystal transformation of an anion exchangeable dynamic metal-organic framework |
| Authors: | Manna, Biplab DESAI, AAMOD V. Kumar, Naveen Karmakar, Avishek GHOSH, SUJIT K. Dept. of Chemistry |
| Keywords: | Single-crystal transformation Dynamic metal Porous aperture Cationic framework 2015 |
| Issue Date: | Mar-2015 |
| Publisher: | Royal Society of Chemistry |
| Citation: | CrystEngComm, 17(46), 8796-8800. |
| Abstract: | A three dimensional (3D) cationic Metal-Organic Framework (MOF) has been fabricated from a neutral N-donor ligand and Cd(ClO4)2. The cationic MOF shows guest triggered inherent dynamic behaviour at room temperature. A single-crystal-to-single-crystal (SCSC) transformation experiment enabled the guest dependent structural dynamism to be well understood. The framework also displays facile anion exchange behaviour and anion dependent structural dynamism. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2196 https://doi.org/10.1039/C5CE00139K |
| ISSN: | 1466-8033 |
| Appears in Collections: | JOURNAL ARTICLES |
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