Chiral biomolecule based dodecanuclear dysprosium(III)-copper(II) clusters: structural analyses and magnetic properties

Please use this identifier to cite or link to this item: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2200

Title:	Chiral biomolecule based dodecanuclear dysprosium(III)-copper(II) clusters: structural analyses and magnetic properties
Authors:	JOARDER, BIPLAB Mukherjee, Soumya Patil, Mahendra Xue, Shufang Tang, Jinkui GHOSH, SUJIT K. Dept. of Chemistry
Keywords:	Chiral biomolecule Structural analyses Magnetic properties Discrete coordination complex 2015
Issue Date:	May-2015
Publisher:	Royal Society of Chemistry
Citation:	Inorganic Chemistry Frontiers, 2(9), 854-859.
Abstract:	An isostructural family of three dodecanuclear chiral M4Cu8 (M = Dy, Y) complexes has been synthesized by adopting a mixed-ligand strategy, wherein one of the constituent linkers, pyroglutamic acid, a recognized biomolecule, has been credibly functioning as the chiral precursor imparting the chirality to the aforementioned complex. The highly symmetric new-fangled M4Cu8 coordination-core, comprising of four square-symmetrically coordinated Dy/Y-vertex sharing M2Cu2 cubane units, has been synthesized as an unprecedented discrete coordination complex, which has been analysed by magnetic measurements.
URI:	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2200 https://doi.org/10.1039/C5QI00090D
ISSN:	2052-1553 2052-1553
Appears in Collections:	JOURNAL ARTICLES

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