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Title: | Ruthenium‐Catalyzed Oxidant‐Free Allylation of Aromatic Ketoximes with Allylic Acetates at Room Temperature |
Authors: | Manikandan, Rajendran Madasamy, Padmaja JEGANMOHAN, MASILAMANI Dept. of Chemistry |
Keywords: | Ruthenium‐Catalyzed Allylation of Aromatic Ketoxime Allylic Acetates Room Temperature Double-bond migration 2015 |
Issue Date: | Sep-2015 |
Publisher: | Wiley |
Citation: | Chemistry - A European Journal, 21(40),13934-13938. |
Abstract: | Substituted aromatic ketoximes reacted efficiently with allylic acetates in the presence of {[RuCl2(p‐cymene)]2} and AgSbF6 in 1,2‐dichloroethane at ambient temperature, providing ortho‐allyl aromatic ketoximes in a highly regioselective manner without an oxidant. In the reaction, the acetate group of allyl acetate acts as a base to activate the CH bond of aromatics. Later, ortho‐allyl aromatic ketoximes were converted into ortho‐allyl aromatic ketones in the presence of HCl. |
URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2213 https://doi.org/10.1002/chem.201502284 |
ISSN: | 0947-6539 1521-3765 |
Appears in Collections: | JOURNAL ARTICLES |
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