Please use this identifier to cite or link to this item: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2213
Title: Ruthenium‐Catalyzed Oxidant‐Free Allylation of Aromatic Ketoximes with Allylic Acetates at Room Temperature
Authors: Manikandan, Rajendran
Madasamy, Padmaja
JEGANMOHAN, MASILAMANI
Dept. of Chemistry
Keywords: Ruthenium‐Catalyzed
Allylation of Aromatic Ketoxime
Allylic Acetates
Room Temperature
Double-bond migration
2015
Issue Date: Sep-2015
Publisher: Wiley
Citation: Chemistry - A European Journal, 21(40),13934-13938.
Abstract: Substituted aromatic ketoximes reacted efficiently with allylic acetates in the presence of {[RuCl2(p‐cymene)]2} and AgSbF6 in 1,2‐dichloroethane at ambient temperature, providing ortho‐allyl aromatic ketoximes in a highly regioselective manner without an oxidant. In the reaction, the acetate group of allyl acetate acts as a base to activate the CH bond of aromatics. Later, ortho‐allyl aromatic ketoximes were converted into ortho‐allyl aromatic ketones in the presence of HCl.
URI: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2213
https://doi.org/10.1002/chem.201502284
ISSN: 0947-6539
1521-3765
Appears in Collections:JOURNAL ARTICLES

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