Please use this identifier to cite or link to this item: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2505
Title: Facile synthesis of aminooxy glycosides by gold(III)-catalyzed glycosidation
Authors: THADKE, SHIVAJI A.
Neralkar, Mahesh
HOTHA, SRINIVAS
Dept. of Chemistry
Keywords: Gold catalysis
Glycosides
Oligosaccharides
Chemical synthesis
Higher oligosaccharides
2016
Issue Date: Jul-2016
Publisher: Elsevier B.V.
Citation: Carbohydrate Research, 430, 16-23.
Abstract: The O-glycosidation of hydroxysuccinimides and hydroxyphthalimides with a variety of aldose derived propargyl 1,2-orthoesters under the gold(III)-catalyzed glycosidation conditions is reported. A wide range of hydroxysuccinimidyl and hydroxyphthalimidyl glycosides were synthesized from corresponding glycosyl orthoesters including glucosyl, mannosyl, galactosyl, ribofuranosyl, arabinofuranosyl, lyxofuranosyl and xylofuranosyl using gold catalysis repertoire. The protocol is identified to be compatible for the synthesis of aminooxy glycosides of higher oligosaccharides as well.
URI: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2505
https://doi.org/10.1016/j.carres.2016.04.022
ISSN: 0008-6215
1873-426X
Appears in Collections:JOURNAL ARTICLES

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