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Title: | Facile synthesis of aminooxy glycosides by gold(III)-catalyzed glycosidation |
Authors: | THADKE, SHIVAJI A. Neralkar, Mahesh HOTHA, SRINIVAS Dept. of Chemistry |
Keywords: | Gold catalysis Glycosides Oligosaccharides Chemical synthesis Higher oligosaccharides 2016 |
Issue Date: | Jul-2016 |
Publisher: | Elsevier B.V. |
Citation: | Carbohydrate Research, 430, 16-23. |
Abstract: | The O-glycosidation of hydroxysuccinimides and hydroxyphthalimides with a variety of aldose derived propargyl 1,2-orthoesters under the gold(III)-catalyzed glycosidation conditions is reported. A wide range of hydroxysuccinimidyl and hydroxyphthalimidyl glycosides were synthesized from corresponding glycosyl orthoesters including glucosyl, mannosyl, galactosyl, ribofuranosyl, arabinofuranosyl, lyxofuranosyl and xylofuranosyl using gold catalysis repertoire. The protocol is identified to be compatible for the synthesis of aminooxy glycosides of higher oligosaccharides as well. |
URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2505 https://doi.org/10.1016/j.carres.2016.04.022 |
ISSN: | 0008-6215 1873-426X |
Appears in Collections: | JOURNAL ARTICLES |
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