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Title: Cobalt-catalyzed C-H olefination of aromatics with unactivated alkenes
Authors: Manoharan, Ramasamy
Sivakumar, Ganesan
Dept. of Chemistry
Keywords: C-H bond functionalization
Cobalt-catalyzed C-H olefination
Unactivated alkenes
Highly regioselective manner
Issue Date: Jul-2016
Publisher: Royal Society of Chemistry
Citation: Chemical Communications, 52(69), 10533-10536.
Abstract: A cobalt-catalyzed C–H olefination of aromatic and heteroaromatic amides with unactivated alkenes, allyl acetates and allyl alcohols is described. This method offers an efficient route for the synthesis of vinyl and allyl benzamides in a highly stereoselective manner. It is observed that the ortho substituent on the benzamide moiety is crucial for the observation of allylated products in unactivated alkenes.
ISSN: 1359-7345
Appears in Collections:JOURNAL ARTICLES

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