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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2509| Title: | Cobalt-catalyzed C-H olefination of aromatics with unactivated alkenes |
| Authors: | Manoharan, Ramasamy Sivakumar, Ganesan JAYAKANNAN, MANICKAM Dept. of Chemistry |
| Keywords: | C-H bond functionalization Cobalt-catalyzed C-H olefination Unactivated alkenes Highly regioselective manner 2016 |
| Issue Date: | Jul-2016 |
| Publisher: | Royal Society of Chemistry |
| Citation: | Chemical Communications, 52(69), 10533-10536. |
| Abstract: | A cobalt-catalyzed C–H olefination of aromatic and heteroaromatic amides with unactivated alkenes, allyl acetates and allyl alcohols is described. This method offers an efficient route for the synthesis of vinyl and allyl benzamides in a highly stereoselective manner. It is observed that the ortho substituent on the benzamide moiety is crucial for the observation of allylated products in unactivated alkenes. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2509 https://doi.org/10.1039/C6CC04835H |
| ISSN: | 1359-7345 1364-548X |
| Appears in Collections: | JOURNAL ARTICLES |
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