Please use this identifier to cite or link to this item: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2633
Title: Wettability of partially suspended graphene
Authors: Ondarcuhu, Thierry
Thomas, Vincent
Nunez, Marc
Dujardin, Erik
RAHMAN, ATIKUR
Black, Charles T.
Checco, Antonio
Dept. of Physics
Keywords: Wettability
Partially suspended graphene
Fabrication
Graphene monolayers transferred
Polymer contamination
Hydrophobic substrates
2016
Issue Date: Apr-2016
Publisher: Nature Publishing Group
Citation: Scientific Reports, 6, 24237.
Abstract: The dependence of the wettability of graphene on the nature of the underlying substrate remains only partially understood. Here, we systematically investigate the role of liquid-substrate interactions on the wettability of graphene by varying the area fraction of suspended graphene from 0 to 95% by means of nanotextured substrates. We find that completely suspended graphene exhibits the highest water contact angle (85° ± 5°) compared to partially suspended or supported graphene, regardless of the hydrophobicity (hydrophilicity) of the substrate. Further, 80% of the long-range water-substrate interactions are screened by the graphene monolayer, the wettability of which is primarily determined by short-range graphene-liquid interactions. By its well-defined chemical and geometrical properties, supported graphene therefore provides a model system to elucidate the relative contribution of short and long range interactions to the macroscopic contact angle.
URI: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2633
https://doi.org/10.1038/srep24237
ISSN: 2045-2322
Appears in Collections:JOURNAL ARTICLES

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