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Title: | Metal assisted cyclomerization of benzodipyrrins into expanded norroles, aza-heptalene and acyclic dimers |
Authors: | GADEKAR, SANTOSH C. REDDY, BADDIGAM K. PANCHAL, SANTOSH P. ANAND, V. G. Dept. of Chemistry |
Keywords: | Cyclomerization Benzodipyrrins Acyclic dimers Macrocyclic framework 2016 |
Issue Date: | Mar-2016 |
Publisher: | Royal Society of Chemistry |
Citation: | Chemical Communications, 52(24), 4565-4568. |
Abstract: | Benzofused dipyrrins react with metal salt copper(II) acetate to predominantly yield a cyclodimer along with a cyclotrimer. N-confused monobenzo-dipyrrin cyclomerized to trioxo-expanded norrole 13a and an acyclic dimer 14 whereas doubly N-confused monobenzo and dibenzo-dipyrrins yielded aza-heptalene 15 and an acyclic dimer 16. |
URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2678 https://doi.org/10.1039/C5CC10356H |
ISSN: | 1359-7345 1364-548X |
Appears in Collections: | JOURNAL ARTICLES |
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