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Title: | High hydroxide conductivity in a chemically stable crystalline metal-organic framework containing a water-hydroxide supramolecular chain |
Authors: | Nagarkar, Sanjog S. Anothumakkool, Bihag DESAI, AAMOD V. Shirolkar, Mandar M. Kurungot, Sreekumar GHOSH, SUJIT K. Dept. of Chemistry |
Keywords: | High hydroxide conductivity Crystalline metal Organic framework Supramolecular chain ion transport mechanism 2016 |
Issue Date: | Jun-2016 |
Publisher: | Royal Society of Chemistry |
Citation: | Chemical Communications, 52(54), 8459-8462. |
Abstract: | A chemically stable cationic MOF encapsulating an in situ formed water-hydroxide supramolecular anionic chain is realized for high hydroxide (OH−) ion conductivity in the solid-state (Type A). High OH− ion conductivity and low activation energy of the MOF demonstrate the advantage of the in situ incorporation of OH− ions to achieve efficient OH− ion conduction in the solid-state. |
URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2696 https://doi.org/10.1039/C6CC04436K |
ISSN: | 1359-7345 1364-548X |
Appears in Collections: | JOURNAL ARTICLES |
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