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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2698| Title: | Harnessing Lewis acidic open metal sites of metal organic frameworks: the foremost route to achieve highly selective benzene sorption over cyclohexane |
| Authors: | Mukherjee, Soumya Manna, Biplab DESAI, AAMOD V. Yin, Yuefeng Krishna, Rajamani Babarao, Ravichandar GHOSH, SUJIT K. Dept. of Chemistry |
| Keywords: | Harnessing Lewis acidic Organic frameworks Benzene sorption Cyclohexane 2016 |
| Issue Date: | May-2016 |
| Publisher: | Royal Society of Chemistry |
| Citation: | Chemical Communications, 52(53), 8215-8218. |
| Abstract: | π-Complexation triggered Lewis acid–base interactions between open metal sites (OMS) of metal–organic frameworks (MOFs), and π-e− rich adsorptive benzene (Bz) is exploited to establish M-MOF-74 as the best Bz-selective MOF sorbent, marking the first report of utilizing OMS behind benzene/cyclohexane separation; a key advance from the energy-economy standpoint of industrial separation. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2698 https://doi.org/10.1039/C6CC03015G |
| ISSN: | 1359-7345 1364-548X |
| Appears in Collections: | JOURNAL ARTICLES |
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