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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3183| Title: | A naphthalene-fused dimer of an anti-aromatic expanded isophlorin |
| Authors: | REDDY, BADDIGAM KIRAN Rawson, Jeff GADEKAR, SANTOSH C. Kgerler, Paul ANAND, V. G. Dept. of Chemistry |
| Keywords: | Naphthalene-fused dimer Isophlorin Aromatic macrocycles Two-electron oxidation NMR spectroscopic Covalent dimer can exist 2017 |
| Issue Date: | Jun-2017 |
| Publisher: | Royal Society of Chemistry |
| Citation: | Chemical Communications, 53(58), 8211-8214. |
| Abstract: | We report the first synthesis of a covalent expanded isophlorin dimer from two 24-π doubly S-confused sapphyrin-like pentathiaisophlorins. It exhibits marginal peripheral aromaticity rather than strong global diatropicity or paratropicity and weak intermacrocycle electronic communication. Quantum chemical methods discern that cross-conjugation is responsible for these unusual electronic features. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3183 https://doi.org/10.1039/C7CC04050D |
| ISSN: | 1359-7345 1364-548X |
| Appears in Collections: | JOURNAL ARTICLES |
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