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DC Field | Value | Language |
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dc.contributor.author | REDDY, BADDIGAM KIRAN | en_US |
dc.contributor.author | Rawson, Jeff | en_US |
dc.contributor.author | GADEKAR, SANTOSH C. | en_US |
dc.contributor.author | Kgerler, Paul | en_US |
dc.contributor.author | ANAND, V. G. | en_US |
dc.date.accessioned | 2019-07-01T05:32:45Z | |
dc.date.available | 2019-07-01T05:32:45Z | |
dc.date.issued | 2017-06 | en_US |
dc.identifier.citation | Chemical Communications, 53(58), 8211-8214. | en_US |
dc.identifier.issn | 1359-7345 | en_US |
dc.identifier.issn | 1364-548X | en_US |
dc.identifier.uri | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3183 | - |
dc.identifier.uri | https://doi.org/10.1039/C7CC04050D | en_US |
dc.description.abstract | We report the first synthesis of a covalent expanded isophlorin dimer from two 24-π doubly S-confused sapphyrin-like pentathiaisophlorins. It exhibits marginal peripheral aromaticity rather than strong global diatropicity or paratropicity and weak intermacrocycle electronic communication. Quantum chemical methods discern that cross-conjugation is responsible for these unusual electronic features. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Royal Society of Chemistry | en_US |
dc.subject | Naphthalene-fused dimer | en_US |
dc.subject | Isophlorin | en_US |
dc.subject | Aromatic macrocycles | en_US |
dc.subject | Two-electron oxidation | en_US |
dc.subject | NMR spectroscopic | en_US |
dc.subject | Covalent dimer can exist | en_US |
dc.subject | 2017 | en_US |
dc.title | A naphthalene-fused dimer of an anti-aromatic expanded isophlorin | en_US |
dc.type | Article | en_US |
dc.contributor.department | Dept. of Chemistry | en_US |
dc.identifier.sourcetitle | Chemical Communications | en_US |
dc.publication.originofpublisher | Foreign | en_US |
Appears in Collections: | JOURNAL ARTICLES |
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