Transition-metal-free synthesis of primary to tertiary carboxamides: A quick access to prodrug-pyrazinecarboxamide

Singh, Ankit; BHAT, RAMAKRISHNA G.; Mete, Trimbak B.

Please use this identifier to cite or link to this item: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3198

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DC Field	Value	Language
dc.contributor.author	Mete, Trimbak B.	en_US
dc.contributor.author	Singh, Ankit	en_US
dc.contributor.author	BHAT, RAMAKRISHNA G.	en_US
dc.date.accessioned	2019-07-01T05:32:46Z
dc.date.available	2019-07-01T05:32:46Z
dc.date.issued	2017-12	en_US
dc.identifier.citation	Tetrahedron Letters, 58(50), 4709-4712.	en_US
dc.identifier.issn	0040-4039	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3198	-
dc.identifier.uri	https://doi.org/10.1016/j.tetlet.2017.11.006	en_US
dc.description.abstract	One-pot expedient and direct carbamoylation of heterocyclics is described. The transformation is realized via direct dehydrogenative aminocarbonylation of heterocyclic compounds under transition-metal-free conditions. This method is regioselective and the protocol is proved to be scalable on a gram scale. Further, the therapeutically useful antitubercular agent pyrazinecarboxamide is successfully synthesized by employing this protocol.	en_US
dc.language.iso	en	en_US
dc.publisher	Elsevier B.V.	en_US
dc.subject	One-pot expedient	en_US
dc.subject	Transition-metal-free	en_US
dc.subject	Caboxamide	en_US
dc.subject	Carbamoylation	en_US
dc.subject	Potassium persul fate	en_US
dc.subject	Heteroaromatic	en_US
dc.subject	2017	en_US
dc.title	Transition-metal-free synthesis of primary to tertiary carboxamides: A quick access to prodrug-pyrazinecarboxamide	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Tetrahedron Letters	en_US
dc.publication.originofpublisher	Foreign	en_US
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