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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3212| Title: | Visible-Light-Triggered Uncaging of Carbonyl Sulfide for Hydrogen Sulfide (H2S) Release |
| Authors: | SHARMA, AJAY KUMAR Nair, Mrutyunjay Chauhan, Preeti Gupta, Kavya Saini, Deepak Kumar CHAKRAPANI, HARINATH Dept. of Chemistry |
| Keywords: | Visible-Light-Triggered Uncaging of Carbonyl Hydrogen Sulfide Carbamothioate Prevalent enzyme 2017 |
| Issue Date: | Sep-2017 |
| Publisher: | American Chemical Society |
| Citation: | Organic Letters, 19 (18), 4822-4825. |
| Abstract: | Generation of hydrogen sulfide (H2S) is challenging and few methods are capable of localized delivery of this gas. Here, a boron dipyrromethene-based carbamothioate (BDP-H2S) that is uncaged by visible light of 470 nm to generate carbonyl sulfide (COS), which is rapidly hydrolyzed to H2S in the presence of carbonic anhydrase, a widely prevalent enzyme, is reported. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3212 https://doi.org/10.1021/acs.orglett.7b02259 |
| ISSN: | 1523-7060 1523-7052 |
| Appears in Collections: | JOURNAL ARTICLES |
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