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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Reja, Rahi M. | en_US |
dc.contributor.author | Sunny, Sereena | en_US |
dc.contributor.author | GOPI, HOSAHUDYA N. | en_US |
dc.date.accessioned | 2019-07-01T05:33:51Z | - |
dc.date.available | 2019-07-01T05:33:51Z | - |
dc.date.issued | 2017-07 | en_US |
dc.identifier.citation | Organic Letters, 19 (13), 3572-3575. | en_US |
dc.identifier.issn | 1523-7060 | en_US |
dc.identifier.issn | 1523-7052 | en_US |
dc.identifier.uri | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3238 | - |
dc.identifier.uri | https://doi.org/10.1021/acs.orglett.7b01498 | en_US |
dc.description.abstract | Synthesis and incorporation of a new amino acid with a nitroalkane side chain into peptides, in situ transformation of a nitroalkane side chain into nitrile oxide, and chemoselective 1,3-dipolar cycloaddition reactions between in situ generated nitrile oxide and different alkynes are reported. The nitroalkane-mediated nitrile oxide–alkyne cycloaddition was found to be orthogonal to the copper(I)-catalyzed azide–alkyne cycloaddition reaction. The combination of orthogonal nitrile oxide–alkyne and azide–alkyne cycloaddition reactions can be explored to tailor different 1,2,3-triazole and 3,5-isoxazoles, respectively, on the peptide backbone. | en_US |
dc.language.iso | en | en_US |
dc.publisher | American Chemical Society | en_US |
dc.subject | Chemoselective Nitrile Oxide-Alkyne | en_US |
dc.subject | Cycloaddition Reactions | en_US |
dc.subject | Nitroalkane-Tethered Peptides | en_US |
dc.subject | Cycloaddition reactions | en_US |
dc.subject | 2017 | en_US |
dc.title | Chemoselective Nitrile Oxide–Alkyne 1,3-Dipolar Cycloaddition Reactions from Nitroalkane-Tethered Peptides | en_US |
dc.type | Article | en_US |
dc.contributor.department | Dept. of Chemistry | en_US |
dc.identifier.sourcetitle | Organic Letters | en_US |
dc.publication.originofpublisher | Foreign | en_US |
Appears in Collections: | JOURNAL ARTICLES |
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