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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3254| Title: | Ruthenium(II)-Catalyzed Redox-Neutral Oxidative Cyclization of Benzimidates with Alkenes with Hydrogen Evolution |
| Authors: | Manikandan, Rajendran Tamizmani, Masilamani JEGANMOHAN, MASILAMANI Dept. of Chemistry |
| Keywords: | Redox-Neutral Oxidative Cyclization Hydrogen Evolution DFT calculations Nitrogen-containing heterocycles 2017 |
| Issue Date: | Dec-2017 |
| Publisher: | American Chemical Society |
| Citation: | Organic Letters, 19 (24), 6678-6681. |
| Abstract: | 1H-Isoindoles and 2H-isoindoles are synthesized via a ruthenium-catalyzed oxidant-free cyclization of benzimidates with alkenes at room temperature with the liberation of H2. Later, 1H-isoindoles were converted into nitrogen-containing heterocycles. The proposed reaction mechanism was strongly supported by experimental evidence and DFT calculations. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3254 https://doi.org/10.1021/acs.orglett.7b03405 |
| ISSN: | 1523-7060 1523-7052 |
| Appears in Collections: | JOURNAL ARTICLES |
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