Please use this identifier to cite or link to this item: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3256
Title: Solvent-controlled selective synthesis of biphenols and quinones via oxidative coupling of phenols
Authors: More, Nagnath Yadav
JEGANMOHAN, MASILAMANI
Dept. of Chemistry
Keywords: Solvent-controlled
Oxidative coupling of phenols
Ambient conditions
Para-para coupling products
2017
Issue Date: Aug-2017
Publisher: Royal Society of Chemistry
Citation: Chemical Communications, 53(69), 9616-9619.
Abstract: A regioselective synthesis of unsymmetrical and symmetrical biphenols and binaphthols via oxidative coupling of phenols or naphthols in the presence of K2S2O8 in CF3COOH under ambient conditions is described. Interestingly, the 1 : 1 ratio of H2O and CH3CN solvent mixtures at 80 °C instead of CF3COOH provided substituted unsymmetrical quinones. A gram-scale synthesis of biphenols and binaphthols was demonstrated.
URI: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3256
https://doi.org/10.1039/C7CC04829G
ISSN: 1359-7345
1364-548X
Appears in Collections:JOURNAL ARTICLES

Files in This Item:
There are no files associated with this item.


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.