Please use this identifier to cite or link to this item:
http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3262Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | PARVIN, NASRINA | en_US |
| dc.contributor.author | DASGUPTA, RAJARSHI | en_US |
| dc.contributor.author | PAL, SHIV | en_US |
| dc.contributor.author | Sen, Sakya S. | en_US |
| dc.contributor.author | KHAN, SHABANA | en_US |
| dc.date.accessioned | 2019-07-01T05:35:12Z | |
| dc.date.available | 2019-07-01T05:35:12Z | |
| dc.date.issued | 2017-04 | en_US |
| dc.identifier.citation | Dalton Transactions, 46(20), 6528-6532. | en_US |
| dc.identifier.issn | 1477-9226 | en_US |
| dc.identifier.issn | 1477-9234 | en_US |
| dc.identifier.uri | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3262 | - |
| dc.identifier.uri | https://doi.org/10.1039/C7DT01055A | en_US |
| dc.description.abstract | The reactivity of structurally identical silylene and stannylene [PhC(NtBu)2EN(SiMe3)2] (E = Si (1) and Sn (2)) towards coinage metals has been explored. While 1 has the propensity to form an adduct with coinage metals (4 and 5), 2 undergoes a ligand exchange reaction with copper halides and silver triflate leading to PhC(NtBu)2SnX (X = Br (6), Cl (7), and OSO2CF3 (8)) with concomitant formation of [M{N(SiMe3)2}] (M = Cu, Ag). However, with AgSbF6 both 1 and 2 led to ion pairs, 9+-SbF6-and 10+-SbF6- displaying weaker Ag?-F interactions in the latter. | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | Royal Society of Chemistry | en_US |
| dc.subject | Strikingly diverse | en_US |
| dc.subject | Stannylene | en_US |
| dc.subject | Functionalized stannylenes | en_US |
| dc.subject | Single crystals | en_US |
| dc.subject | 2017 | en_US |
| dc.title | Strikingly diverse reactivity of structurally identical silylene and stannylene | en_US |
| dc.type | Article | en_US |
| dc.contributor.department | Dept. of Chemistry | en_US |
| dc.identifier.sourcetitle | Dalton Transactions | en_US |
| dc.publication.originofpublisher | Foreign | en_US |
| Appears in Collections: | JOURNAL ARTICLES | |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.