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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3268| Title: | Direct coordination of a germanium(II) dicationic center to transition metals |
| Authors: | Rauta, Ravindra K. MAJUMDAR, MOUMITA Dept. of Chemistry |
| Keywords: | Direct coordination Dicationic center Transition metals Azamacrocycles 2017 |
| Issue Date: | Jan-2017 |
| Publisher: | Royal Society of Chemistry |
| Citation: | Chemical Communications, 53(9), 1467-1469 . |
| Abstract: | The germanium(II) center of dicationic compound 1 donates an electron pair to transition metal Ag(I) and Au(I) cations, leading to complexes 2 and 3 respectively. Complex 3 is stabilized by [Ge:]2+→Au(I) σ-donation and π-back donation from filled d-orbitals of Au(I) to the two sets of p-orbitals available on Ge(II) centers. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3268 https://doi.org/10.1039/C6CC09525A |
| ISSN: | 1359-7345 1364-548X |
| Appears in Collections: | JOURNAL ARTICLES |
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