Please use this identifier to cite or link to this item: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3284
Title: Reverse Intramolecular Stacking in o‐Xylene Bridge Symmetrical Dimers of 2‐Thiopyridine Derivative: Assessment of the Conformational Stability
Authors: Kumar, Ranjeet
Gaurav, Archana
PAL, SHIV
Kumar, Krishnan R.
Sridhar, Balasubramanian
Tewari, Ashish K.
Dept. of Chemistry
Keywords: Reverse Intramolecular
Conformational Stability
2-Thiopyridine Derivative
Conformational analysis
DFT calculations
Hirshfeld surface analysis
2017
Issue Date: Apr-2017
Publisher: Wiley
Citation: ChemistrySelect, 2(11), 3249-3255.
Abstract: Herein, we report o‐xylene based symmetrical dimers of 2‐thiopyridine derivative for studies of intramolecular stacking and conformational analysis 1‐3. The conformational analyses of all compounds have been carried out in solid, solution and gaseous states. Interestingly, all compounds showed reverse intramolecular stacked conformation between contiguous rings. Among all, compound 3 has shown polymorphism properties that also shown reverse intramolecular stacked conformation. The polymorphic studies have been achieved through single crystal X‐ray diffraction, intermolecular interactions in their crystal packing, overlay diagram, DSC analysis and Hirshfeld surface analysis.
URI: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3284
https://doi.org/10.1002/slct.201700269
ISSN: 2365-6549
Appears in Collections:JOURNAL ARTICLES

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