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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3313| Title: | Ultra‐microporous Metal–Organic Framework Built from Rigid Linkers Showing Structural Flexibility Resulting in a Marked Change in Carbon Dioxide Capacity |
| Authors: | Banerjee, Aparna Chakraborty, Debanjan VAIDHYANATHAN, RAMANATHAN Dept. of Chemistry |
| Keywords: | Microporous materials Built from Rigid Linkers Showing Structural Flexibility Carbon Dioxide Capacity 2017 |
| Issue Date: | May-2017 |
| Publisher: | Wiley |
| Citation: | European Journal of Inorganic Chemistry, 2017(18), 2464-2468. |
| Abstract: | An ultra‐microporous CoHAtzOx (HAtz = aminotriazole, Ox = oxalate) metal–organic framework with a 3D framework showing guest‐dependent reversible structural transformations was studied. The flexibility was found to arise from buckling of the rigid Co–Ox and Co–HAtz chains, which yields a desolvated structure with a 78 % lower void volume and significantly lower CO2 capacity. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3313 https://doi.org/10.1002/ejic.201700107 |
| ISSN: | 1434-1948 1099-0682 |
| Appears in Collections: | JOURNAL ARTICLES |
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